The Wassenaar Arrangement (WA) is an international framework that was established with the objective of “promoting transparency and greater responsibility in transfers of conventional arms and dual-use goods and technologies.”

Within its Munitions List 7 (ML7), the Wassenaar Arrangement features chemical agents, biological agents, riot control agents, radioactive materials, related equipment, components, and materials.

In particular, with regards to chemical agents, ML7 comprises all of the CWC Schedule 1 chemicals, the central incapacitating agent 3-quinuclidinyl benzilate (BZ), which is a CWC Schedule 2 chemical, as well as a list of defoliants and a list of riot control agents, neither of which is in the CWC schedules.

The table below lists all of the entries of the Wassenaar Arrangement’s Munitions List 7 (ML7), curated and structurally annotated. An “Overlap Analysis” column shows the corresponding entries in the CWC Schedules, the AG Chemical Weapons Precursors list, and the World Customs Organization STCE strategic chemicals, and the Syria-related Council Regulation (EU) No 36/2012 Annex Ia and Annex IX chemicals.

New. The table is now downloadable in SDF, CSV, and Microsoft Excel format.

Costanzi Research Logo Wassenaar Arrangement (WA) Munitions List 7 (ML7) Chemicals

Curated and Structurally Annotated by Costanzi Research – www.costanziresearch.com
(Last Update: November 12, 2021)

The Table is available for download in the following formats:
SDF, CSV, Microsoft Excel

Disclaimer. The information in this table is provided for research and general information purposes only. The authors do not guarantee the accuracy of the information and do not take any responsibility for any consequence, including, but not limited to, financial or legal consequences, that may occur due to inaccuracies or omissions.
Color Code: Individual Chemicals
Mixtures of Chemicals
Proteins
Families of Chemicals
Examples: Individual Compounds Belonging to a Family of Chemicals
Exceptions: Compounds Belonging to a Family of Chemicals but Excluded from the CWC Schedules
Polymers
 Notes.
1. For entry ML7 b.4.b (Agent Orange), there is a discrepancy between the name, which indicates the free acid form, and the CAS number, which indicates the butyl ester form.
2. CAS Registry Numbers® are the intellectual property of the American Chemical Society; and are used by Licensee with the express permission of CAS. CAS Registry Numbers® are Verified by CAS unless noted by a *. For entries lacking a CAS Registry Number®, a sequential registry number assigned by Costanzi Research (CR number) is provided instead.
3. For proteins, the UNIPROT ID is provided instead.
4. Overlaps with CWC schedules, Australia Group chemicals, Wassenaar ML7 chemicals, WCO STCE Strategic Chemicals, and Council Regulation (EU) No 36/2012 Annex Ia and Annex IX chemicals are provided.
5. 2D structures curated by Costanzi Research are provided as SDF and MRV files (MRV files require ChemAxon’s MarvinSketch to open).
6. 3D strucures from PubChem are shown with NCBI’s iCn3D.
7. NIST Chemistry WebBook cards provide chemical and physical data compiled by the National Institute of Standards and Technology, including, inter alia, analytical spectra.
Category WA Entry Number1 WA Entry Name CAS Registry Number® 2 PubChem ID3 Structure
(click to enlarge)		 SMILES InChI Overlaps4 Links5-7
Nerve agents WA ML7 b.1.a O-Alkyl (<=C10, incl. cycloalkyl) alkyl (Me, Et, n-Pr or i-Pr)-phosphonofluoridates CR0001 — work in progress - Image coming soon — —CWC 1A1 —
Nerve agents WA ML7 b.1.a Example 1 Sarin: O-Isopropyl methylphosphonofluoridate 107-44-8 7871 work in progress - Image coming soon CC(C)O[P](C)(F)=O InChI=1S/C4H10FO2P/c1-4(2)7-8(3,5)6/h4H,1-3H3

InChIKey=DYAHQFWOVKZOOW-UHFFFAOYSA-N		 CWC 1A1 Example 1

STCE 28
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Nerve agents WA ML7 b.1.a Example 2 Soman: O-Pinacolyl methylphosphonofluoridate 96-64-0 7305 work in progress - Image coming soon CC(O[P](C)(F)=O)C(C)(C)C InChI=1S/C7H16FO2P/c1-6(7(2,3)4)10-11(5,8)9/h6H,1-5H3

InChIKey=GRXKLBBBQUKJJZ-UHFFFAOYSA-N		 CWC 1A1 Example 2

STCE 18
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Nerve agents WA ML7 b.1.b O-Alkyl (<=C10, incl. cycloalkyl) N,N-dialkyl (Me, Et, n-Pr or i-Pr) phosphoramidocyanidates CR0002 — work in progress - Image coming soon — —CWC 1A2 —
Nerve agents WA ML7 b.1.b Example 1 Tabun:O-Ethyl N,N-dimethyl phosphoramidocyanidate 77-81-6 6500 work in progress - Image coming soon CCO[P](=O)(C#N)N(C)C InChI=1S/C5H11N2O2P/c1-4-9-10(8,5-6)7(2)3/h4H2,1-3H3

InChIKey=PJVJTCIRVMBVIA-UHFFFAOYSA-N		 CWC 1A2 Example 1

STCE 15
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Nerve agents WA ML7 b.1.c O-Alkyl (H or <=C10, incl. cycloalkyl) S-2-dialkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr) phosphonothiolates and corresponding alkylated or protonated salts CR0003 — work in progress - Image coming soon — —CWC 1A3 —
Nerve agents WA ML7 b.1.c Example 1 VX: O-Ethyl S-2-diisopropylaminoethyl methyl phosphonothiolate 50782-69-9 39793 work in progress - Image coming soon CCO[P](C)(=O)SCCN(C(C)C)C(C)C InChI=1S/C11H26NO2PS/c1-7-14-15(6,13)16-9-8-12(10(2)3)11(4)5/h10-11H,7-9H2,1-6H3

InChIKey=JJIUCEJQJXNMHV-UHFFFAOYSA-N		 CWC 1A3 Example 1

STCE 242
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Vesicants (Sulfur mustards) WA ML7 b.2.a.1 2-Chloroethylchloromethylsulfide 2625-76-5 14557887 work in progress - Image coming soon C(CCl)SCCl InChI=1S/C3H6Cl2S/c4-1-2-6-3-5/h1-3H2

InChIKey=HHQVSDLFPSFPST-UHFFFAOYSA-N		 CWC 1A4-1

STCE 111
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Vesicants (Sulfur mustards) WA ML7 b.2.a.2 Mustard gas: Bis(2-chloroethyl)sulfide 505-60-2 10461 work in progress - Image coming soon ClCCSCCCl InChI=1S/C4H8Cl2S/c5-1-3-7-4-2-6/h1-4H2

InChIKey=QKSKPIVNLNLAAV-UHFFFAOYSA-N		 CWC 1A4-2

STCE 51
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Vesicants (Sulfur mustards) WA ML7 b.2.a.3 Bis(2-chloroethylthio)methane 63869-13-6 522107 work in progress - Image coming soon ClCCSCSCCCl InChI=1S/C5H10Cl2S2/c6-1-3-8-5-9-4-2-7/h1-5H2

InChIKey=RKTJTTAEKCRXNL-UHFFFAOYSA-N		 CWC 1A4-3

STCE 249
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Vesicants (Sulfur mustards) WA ML7 b.2.a.4 Sesquimustard: 1,2-Bis(2-chloroethylthio)ethane 3563-36-8 19092 work in progress - Image coming soon ClCCSCCSCCCl InChI=1S/C6H12Cl2S2/c7-1-3-9-5-6-10-4-2-8/h1-6H2

InChIKey=AMGNHZVUZWILSB-UHFFFAOYSA-N		 CWC 1A4-4

STCE 120
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Vesicants (Sulfur mustards) WA ML7 b.2.a.5 1,3-Bis(2-chloroethylthio)-n-propane 63905-10-2 522108 work in progress - Image coming soon C(CSCCCl)CSCCCl InChI=1S/C7H14Cl2S2/c8-2-6-10-4-1-5-11-7-3-9/h1-7H2

InChIKey=YHRGRBPJIRKFND-UHFFFAOYSA-N		 CWC 1A4-5

STCE 250
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Vesicants (Sulfur mustards) WA ML7 b.2.a.6 1,4-Bis(2-chloroethylthio)-n-butane 142868-93-7 518918 work in progress - Image coming soon ClCCSCCCCSCCCl InChI=1S/C8H16Cl2S2/c9-3-7-11-5-1-2-6-12-8-4-10/h1-8H2

InChIKey=AYSIRJGVBLMLAS-UHFFFAOYSA-N		 CWC 1A4-6

STCE 293
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Vesicants (Sulfur mustards) WA ML7 b.2.a.7 1,5-Bis(2-chloroethylthio)-n-pentane 142868-94-8 22608774 work in progress - Image coming soon ClCCSCCCCCSCCCl InChI=1S/C9H18Cl2S2/c10-4-8-12-6-2-1-3-7-13-9-5-11/h1-9H2

InChIKey=CUJOZMZOOCTTAZ-UHFFFAOYSA-N		 CWC 1A4-7

STCE 294
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Vesicants (Sulfur mustards) WA ML7 b.2.a.8 Bis(2-chloroethylthiomethyl)ether 63918-90-1 22608780 work in progress - Image coming soon C(CCl)SCOCSCCCl InChI=1S/C6H12Cl2OS2/c7-1-3-10-5-9-6-11-4-2-8/h1-6H2

InChIKey=IJGBNRTYNRKNHS-UHFFFAOYSA-N		 CWC 1A4-8

STCE 252
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Vesicants (Sulfur mustards) WA ML7 b.2.a.9 O-Mustard: Bis(2-chloroethylthioethyl)ether 63918-89-8 45452 work in progress - Image coming soon ClCCSCCOCCSCCCl InChI=1S/C8H16Cl2OS2/c9-1-5-12-7-3-11-4-8-13-6-2-10/h1-8H2

InChIKey=FWVCSXWHVOOTFJ-UHFFFAOYSA-N		 CWC 1A4-9

STCE 251
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Vesicants (Lewisites) WA ML7 b.2.b.1 Lewisite 1: 2-Chlorovinyldichloroarsine 541-25-3 5372798 work in progress - Image coming soon C(=C[As](Cl)Cl)Cl InChI=1S/C2H2AsCl3/c4-2-1-3(5)6/h1-2H/b2-1+

InChIKey=GIKLTQKNOXNBNY-OWOJBTEDSA-N		 CWC 1A5-1

STCE 59
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Vesicants (Lewisites) WA ML7 b.2.b.2 Lewisite 2: Bis(2-chlorovinyl)chloroarsine 40334-69-8 5368106 work in progress - Image coming soon ClC=C[As](Cl)C=CCl InChI=1S/C4H4AsCl3/c6-3-1-5(8)2-4-7/h1-4H/b3-1+,4-2+

InChIKey=YRFJGLQNTWLXKO-ZPUQHVIOSA-N		 CWC 1A5-2

STCE 235
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Vesicants (Lewisites) WA ML7 b.2.b.3 Lewisite 3: Tris(2-chlorovinyl)arsine 40334-70-1 5352143 work in progress - Image coming soon ClC=C[As](C=CCl)C=CCl InChI=1S/C6H6AsCl3/c8-4-1-7(2-5-9)3-6-10/h1-6H/b4-1+,5-2+,6-3+

InChIKey=AOAVIJUEFJPSAI-GZDDRBCLSA-N		 CWC 1A5-3

STCE 236
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Vesicants (Nitrogen mustards) WA ML7 b.2.c.1 HN1: Bis(2-chloroethyl)ethylamine 538-07-8 10848 work in progress - Image coming soon CCN(CCCl)CCCl InChI=1S/C6H13Cl2N/c1-2-9(5-3-7)6-4-8/h2-6H2,1H3

InChIKey=UQZPGHOJMQTOHB-UHFFFAOYSA-N		 CWC 1A6-1

STCE 57
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Vesicants (Nitrogen mustards) WA ML7 b.2.c.2 HN2: Bis(2-chloroethyl)methylamine 51-75-2 4033 work in progress - Image coming soon CN(CCCl)CCCl InChI=1S/C5H11Cl2N/c1-8(4-2-6)5-3-7/h2-5H2,1H3

InChIKey=HAWPXGHAZFHHAD-UHFFFAOYSA-N		 CWC 1A6-2

STCE 1
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Vesicants (Nitrogen mustards) WA ML7 b.2.c.3 HN3: Tris(2-chloroethyl)amine 555-77-1 5561 work in progress - Image coming soon C(CCl)N(CCCl)CCCl InChI=1S/C6H12Cl3N/c7-1-4-10(5-2-8)6-3-9/h1-6H2

InChIKey=FDAYLTPAFBGXAB-UHFFFAOYSA-N		 CWC 1A6-3

STCE 60
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Central incapacitants WA ML7 b.3.a BZ: 3-Quinuclidinyl benzilate (*) 6581-06-2 23056 work in progress - Image coming soon OC(C(=O)OC1CN2CCC1CC2)(c3ccccc3)c4ccccc4 InChI=1S/C21H23NO3/c23-20(25-19-15-22-13-11-16(19)12-14-22)21(24,17-7-3-1-4-8-17)18-9-5-2-6-10-18/h1-10,16,19,24H,11-15H2

InChIKey=HGMITUYOCPPQLE-UHFFFAOYSA-N		 CWC 2A3

STCE 138
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Defoliants WA ML7 b.4.a Butyl 2-chloro-4-fluorophenoxyacetate (LNF) 1692-85-9 54941708 work in progress - Image coming soon CCCCOC(=O)COC1=C(Cl)C=C(F)C=C1 InChI=1S/C12H14ClFO3/c1-2-3-6-16-12(15)8-17-11-5-4-9(14)7-10(11)13/h4-5,7H,2-3,6,8H2,1H3

InChIKey=IDEJTUXAJQPPPL-UHFFFAOYSA-N		 —
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Defoliants WA ML7 b.4.b Free Acid Form 2,4,5-trichlorophenoxyacetic acid mixed with 2,4-dichlorophenoxyacetic acid (Agent Orange)

Note: this is the entry name given in ML7		 8015-35-8

Note: this CAS Registry Number® is not given in ML7 but can be inferred from the name given in ML7		 24683 work in progress - Image coming soon O=C(O)COC1=CC=C(Cl)C=C1Cl.O=C(O)COC1=CC(Cl)=C(Cl)C=C1Cl nChI=1S/C8H5Cl3O3.C8H6Cl2O3/c9-4-1-6(11)7(2-5(4)10)14-3-8(12)13;9-5-1-2-7(6(10)3-5)13-4-8(11)12/h1-2H,3H2,(H,12,13);1-3H,4H2,(H,11,12)

InChIKey=WWPVVPNDJBRXMS-UHFFFAOYSA-N		 —
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Defoliants WA ML7 b.4.b Butyl Ester Form 2,4,5-trichlorophenoxyacetic acid butyl ester mixed with 2,4-dichlorophenoxyacetic acid butyl ester (Agent Orange)

Note: this name is not given in ML7 but can inferred from the CAS Registry Number® given in ML7 (39277-47-9)		 39277-47-9

Note: this is the entry CAS Registry Number® given in ML7		 38264 work in progress - Image coming soon O=C(OCCCC)COC1=CC=C(Cl)C=C1Cl.O=C(OCCCC)COC1=CC(Cl)=C(Cl)C=C1Cl InChI=1S/C12H13Cl3O3.C12H14Cl2O3/c1-2-3-4-17-12(16)7-18-11-6-9(14)8(13)5-10(11)15;1-2-3-6-16-12(15)8-17-11-5-4-9(13)7-10(11)14/h5-6H,2-4,7H2,1H3;4-5,7H,2-3,6,8H2,1H3

InChIKey=OLAOGBRYSBMLAO-UHFFFAOYSA-N		 STCE 234
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Defoliants WA ML7 b.4.b Component 1 2,4,5-trichlorophenoxyacetic acid 93-76-5 1480 work in progress - Image coming soon OC(=O)COc1cc(Cl)c(Cl)cc1Cl InChI=1S/C8H5Cl3O3/c9-4-1-6(11)7(2-5(4)10)14-3-8(12)13/h1-2H,3H2,(H,12,13)

InChIKey=SMYMJHWAQXWPDB-UHFFFAOYSA-N		 —
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Defoliants WA ML7 b.4.b Component 2 2,4-dichlorophenoxyacetic acid 94-75-7 1486 work in progress - Image coming soon OC(=O)COc1ccc(Cl)cc1Cl InChI=1S/C8H6Cl2O3/c9-5-1-2-7(6(10)3-5)13-4-8(11)12/h1-3H,4H2,(H,11,12)

InChIKey=OVSKIKFHRZPJSS-UHFFFAOYSA-N		 —
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Precursors WA ML7 c.1 Alkyl (Me, Et, n-Pr or i-Pr) phosphonyldifluorides CR0004 — work in progress - Image coming soon — —CWC 1B9

AG 4, 23

STCE 74		 —
Precursors WA ML7 c.1 Example 1 DF: Methylphosphonyldifluoride 676-99-3 69610 work in progress - Image coming soon C[P](F)(F)=O InChI=1S/CH3F2OP/c1-5(2,3)4/h1H3

InChIKey=PQIOSYKVBBWRRI-UHFFFAOYSA-N		 CWC 1B9 Example 1

AG 4

STCE 69
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Precursors WA ML7 c.2 O-Alkyl (H or <=C10, incl. cycloalkyl) O-2-dalkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr) phosphonites and corresponding alkylated or protonated salts CR0005 — work in progress - Image coming soon — —CWC 1B10

AG 29		 —
Precursors WA ML7 c.2 Example 1 QL: O-Ethyl O-2-diisopropylaminoethyl methylphosphonite 57856-11-8 170325 work in progress - Image coming soon CCOP(C)OCCN(C(C)C)C(C)C InChI=1S/C11H26NO2P/c1-7-13-15(6)14-9-8-12(10(2)3)11(4)5/h10-11H,7-9H2,1-6H3

InChIKey=OIQVKKOBTVZIFE-UHFFFAOYSA-N		 CWC 1B10 Example 1

AG 29

STCE 246
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Precursors WA ML7 c.3 Chlorosarin: O-Isopropyl methylphosphonochloridate 1445-76-7 102124 work in progress - Image coming soon CC(C)O[P](C)(Cl)=O InChI=1S/C4H10ClO2P/c1-4(2)7-8(3,5)6/h4H,1-3H3

InChIKey=RHAHLPAWJVKXAZ-UHFFFAOYSA-N		 CWC 1B11

STCE 103
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Precursors WA ML7 c.4 Chlorosoman: O-Pinacolyl methylphosphonochloridate 7040-57-5 145983 work in progress - Image coming soon CC(O[P](C)(Cl)=O)C(C)(C)C InChI=1S/C7H16ClO2P/c1-6(7(2,3)4)10-11(5,8)9/h6H,1-5H3

InChIKey=XVNBZVNXJMOQEX-UHFFFAOYSA-N		 CWC 1B12

STCE 140
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Riot control agents WA ML7 d.1 α-Bromobenzeneacetonitrile, (Bromobenzyl cyanide) (CA) 5798-79-8 22044 work in progress - Image coming soon BrC(C#N)c1ccccc1 InChI=1S/C8H6BrN/c9-8(6-10)7-4-2-1-3-5-7/h1-5,8H

InChIKey=XUHFBOUSHUEAQZ-UHFFFAOYSA-N		 STCE 131
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Riot control agents WA ML7 d.2 [(2-chlorophenyl) methylene] propanedinitrile, (o-Chlorobenzylidenemalononitrile) (CS) 2698-41-1 17604 work in progress - Image coming soon Clc1ccccc1C=C(C#N)C#N InChI=1S/C10H5ClN2/c11-10-4-2-1-3-9(10)5-8(6-12)7-13/h1-5H

InChIKey=JJNZXLAFIPKXIG-UHFFFAOYSA-N		 STCE 113
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Riot control agents WA ML7 d.3 2-Chloro-1-phenylethanone, Phenylacyl chloride (ω-chloroacetophenone) (CN) 532-27-4 10757 work in progress - Image coming soon ClCC(=O)c1ccccc1 InChI=1S/C8H7ClO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2

InChIKey=IMACFCSSMIZSPP-UHFFFAOYSA-N		 STCE 56
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Riot control agents WA ML7 d.4 Dibenz-(b,f)-1,4-oxazephine, (CR) 257-07-8 9213 work in progress - Image coming soon O1c2ccccc2C=Nc3ccccc13 InChI=1S/C13H9NO/c1-3-7-12-10(5-1)9-14-11-6-2-4-8-13(11)15-12/h1-9H

InChIKey=NPUACKRELIJTFM-UHFFFAOYSA-N		 STCE 43
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Riot control agents WA ML7 d.5 10-Chloro-5,10-dihydrophenarsazine, (Phenarsazine chloride), (Adamsite), (DM) 578-94-9 11362 work in progress - Image coming soon Cl[As]1c2ccccc2Nc3ccccc13 InChI=1S/C12H9AsClN/c14-13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)13/h1-8,15H

InChIKey=PBNSPNYJYOYWTA-UHFFFAOYSA-N		 STCE 62
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Riot control agents WA ML7 d.6 N-Nonanoylmorpholine, (MPA) 5299-64-9 79182 work in progress - Image coming soon CCCCCCCCC(=O)N1CCOCC1 InChI=1S/C13H25NO2/c1-2-3-4-5-6-7-8-13(15)14-9-11-16-12-10-14/h2-12H2,1H3

InChIKey=NBRDJXSTGSUITP-UHFFFAOYSA-N		 STCE 129
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